Yeah, but you'd have to have a totally seperate bank of batteries and battery charger for the 24 volt bank. The 12 volt is usually achieved by having a generator designed to use 12 volts for starting, and you can run your electronics off of that, and it too needs it's own battery charger. I agree with Kiwi, if you're going to repower ditch the 32 volt system, and switch your engine and house batteries over to 24 volts as well as all of your systems. You shouldnt have too many systems to convert. You can also use like a Newmar transformer for different voltage on small items but they don't work as well as batteries at that voltage.